Chloride stress corrosion cracking of an austenitic. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no. Stress corrosion cracking of austenitic stainless steels 689 ld. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. Influence of carbide precipitation and rolling direction on intergranular stress corrosion cracking of austenitic stainless steels in hydrogenated hightemperature water k. This diagram figure 1 is analogous to a similar diagram for caustic.
The interaction of corrosion fatigue and stresscorrosion. Mili24244 is a us dept of defense specification for insulation that is going to be used on the stainless steel pipe and equipment associated with nuclear propulsion. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stainless steels are more resistant to general corrosion compared with carbon steel. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. On the stress corrosion cracking mechanisms of austenitic. Super duplex and super austenitic stainless steels are considered virtually immune to chloride stress cracking.
Stress corrosion cracking scc of duplex stainless steel. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Uns s32100 type austenitic stainless steel nozzle fitting at a low point in the reactor effluent piping in a gasoil hydrotreater unit following start up.
A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Not only can duplex stainless steel hold up reliably through trauma impact, but through corrosion as well. Pdf stress corrosion cracking of austenitic stainless steels in. Surface finishing treatments such as shot blasting and wire brushing can be beneficial in improving the integrity of machined surfaces of austenitic stainless steels. This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Grades with high resistance to chlorideinduced stress corrosion cracking scc duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Effects of marine environments on stress corrosion cracking. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated. Austenitic grades, however, are susceptible to chloride stress corrosion cracking scc and are not recommended for service that combines tensile stress and the presence of chlorides, even at moderate temperatures. Stress corrosion cracking scc of austenitic stainless steels in high. This alloy exhibits superior resistance to stresscorrosion cracking in boiling 2040% sulfuric acid.
The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Hydrogen embrittlement cracking of superduplex steel twi. In both steels the coldworked material cw showed higher crack propagation rate than annealed one st, where the variation of the propagated crystal planes of. Why are austenitic stainless steels more susceptible to. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. The effect of cold work on stresscorrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Austenitic stainless steels are used in a wide range of applications, including. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Austenitic refers to an alloy consisting mainly of austenite. Intergranular stress corrosion cracking of welded steel twi. Stress corrosion cracking scc is a common issue with many specialty alloys. Quasicleavage facets have been detected in the stress corrosion cracking fracture of type 304 and type 316 austenitic stainless steels under an environment containing chloride. In essence, on their own, ferritic stainless steel and austenitic stainless steel dont handle stress corrosion cracking admirably. Rr902 chloride stress corrosion cracking in austenitic. Chloride stress corrosion cracking of an austenitic stainless. Chloride stress corrosion cracking inspectioneering. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride.
Austenitic stainless steels are widely used in hydroprocessing units. Stress corrosion cracking of an austenitic stainless steel. Effects of potential and stress on stress corrosion cracking. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Duplex stainless steels, austenitic stainless steels with a high nickel content 25. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Austenitic stainless steels chloride induced stress. Arioka 1 inss institute of nuclear safety system, 64 sata, mihamacho, fukui 9191205, japan. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Stress corrosion cracking scc of austenitic stainless steel weld metal. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. The effect of cold work on the stresscorrosion cracking of.
Effects of marine environments on stress corrosion. Chloride stress corrosion cracking in austenitic stainless. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Duplex stainless steel has become more and more popular for its combination of strength and affordability. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Stress corrosion cracking the international institute of. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. In this study, ground steel surfaces were subjected to a series of sand blasting and wire brushing.
Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. To understand the corrosion resistance properties of duplex stainless steel, you must also understand the concept of stress corrosion cracking. For this reason, they cant be used to serve a number of different functions. Alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Their morphology and crystal orientation were analyzed. The most widely used grade of stainless steel is austenitic. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. Duplex stainless steels, austenitic stainless steels with a high nickel content 25%.
Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to. Cracking occurred in a uns s32100 type austenitic stainless steel nozzle fitting at a low point in the reactor effluent piping in a gasoil hydrotreater unit following start up. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. The scc propensity of austenitic stainless steels in marine environments is affected by many variables including the amount of moisture and time of wetness, airborne contaminants e. Intergranular stress corrosion cracking resistance of. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Grades with high resistance to chlorideinduced stress corrosion cracking scc. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Feb 28, 2018 however, ferritic steel is still fairly vulnerable to stress corrosion cracking.
The effect of cold work on the stresscorrosion cracking. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The welding of austenitic stainless steel has two major problems, namely hot cracking of weld metal and sensitisation of the haz. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Austenitic alloys contain a high percentage of nickel and chromium, which makes them, and the steel made from them, very resistant to corrosion. The chemicalmechanical correlation model for stress corrosion cracking scc was used to analyize the effect of electrode potential e on scc of austenitic stainless steels ss in. Polythionic acid stress corrosion cracking deterioration.
Pitting and stress corrosion cracking behavior of austenitic stainless steel weldments containing retained ferrite. Stress corrosion cracking of austenitic stainless steels. Stress corrosion cracking international institute of. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Effects of surface preparation on pitting resistance. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Behaviour of stress corrosion cracking of austenitic stainless. Hot cracking is due to the inability of the solidifying weld metal to bear the strains, arising during solidification in a certain temperature range. The following sandvik grades have very good or excellent resistance to chlorideinduced stress corrosion cracking. There is a synergistic relationship between dissolved oxygen and the chloride level. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks.
Mechanisms of stresscorrosion cracking asm international. Effects of stress and temperature on stress corrosion. They can be subject to polythionic acid stress corrosion cracking during shut down. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Pdf stress corrosion cracking of austenitic stainless. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Ferritic steels are also resistant to cracking but may corrode. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. Stress corrosion cracking scc of austenitic stainless and. Jun 06, 2019 alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless.
Ss 316 austenitic stainless steel grade steelindo persada. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. It can be detrimental to austenitic stainless steels, one of the main reasons. Effects of potential and stress on stress corrosion. Stress corrosion cracking of austenitic stainless steel technical bulletin ind tb009 02212020 replaces 011918 two other common specifications are mili24244 and nrc 1. The nickel content in austenitic stainless steels helps to reduce the rate of corrosion, particularly in acid environments. Irradiationinduced stress corrosion cracking of austenitic stainless steels. The effect of salt loading on chlorideinduced stress. Chloride stress corrosion cracking in austenitic stainless steel. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime. Stress corrosion cracking in duplex stainless steel great. Influence of sensitization on crack growth rate of aisi 304 stainless steel as a. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution.
These operations optimize inservice properties such as resistance to pitting corrosion and stress corrosion cracking scc. Ahmed and others published stress corrosion cracking of austenitic stainless steels in chloride environment find. Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6. Stress corrosion cracking of an austenitic stainless steel in. Caustic stress corrosion cracking inspectioneering. This limits the usefulness of austenitic stainless steel for containing. Chloride stress corrosion cracking is a well known form of scc, typically caused. Stress corrosion cracking scc of austenitic stainless. T1 effects of stress and temperature on stress corrosion cracking of austenitic stainless steels in concentrated magnesium chloride solutions. Crystal orientation analysis on stress corrosion cracking. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings.
The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. The chemicalmechanical correlation model for stress corrosion cracking scc was used to analyize the effect of electrode potential e on scc of austenitic stainless steels ss in concentrated chloride solutions. Effects of marine environments on stress corrosion cracking of austenitic stainless steels 1011820 effective december 6, 2006, this report has been made publicly available in accordance with section 734. Stress corrosion cracking in duplex stainless steel. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Stress corrosion cracking facts and how to reduce the risk.